
Comparison of hydrocolloid properties -3
|
Name |
methyl cellulose (E461) |
pectin (E440) low methoxyl (LM) |
pectin (E440) high methoxyl (HM) |
sodium alginate (E401) |
xanthan (E415) |
|
Origin |
a modified polysaccharide derived from cellulose rich plants. |
polysaccharide derived from citrus peel and apple pomace. |
polysaccharide derived from citrus peel and apple pomace. |
polysaccharide extracted from brown algae. |
polysaccharide obtained by fermentation of Xanthomonas campestris |
|
Texture |
thermoreversible soft elastic gel when heated; helps form and stabilize foams when cold |
thermoreversible gels |
thermoirreversible gels |
thermoirreversible gel in presence of calcium ions; shear-thinning thickener in absence of calcium |
high viscosity, shear-thinning; thermoreversible soft elastic gels w. locust bean gum or konjac |
|
Clarity |
|
clear, transparent |
clear, transparent |
clear, transparent |
clear, mostly transparent |
|
Dispersion |
hot or cold water, use slow speed to avoid foaming; mix with small amount of hot water to avoid lumps and stir into the rest of the cold water |
cold water; d. can be improved by mixing with sugar (3-5x) |
cold water; d. can be improved by mixing with sugar (3-5x) |
cold water; d. can be improved by mixing with sugar (3-5x); add. of acidic liquids may cause precipitation of alginic acid |
cold or hot water; d. can be improved by mixing with sugar (10x) or glycerol, alcohol or vegetable oil. |
|
Hydration (dissolution) |
cold water, leave over night; add salt after complete hydration |
cold or hot water |
cold or hot water; will not dissolve if > 25% sugar |
cold or hot water; if cold, allow to hydrate for a couple of hours |
cold or hot water; does not hydrate at high sugar concentrations (>65%). |
|
pH |
2-13 |
2.5-5.5 |
2.5-4 |
2.8-10 |
1-13 |
|
Setting |
gels when heated to 50-60 °C |
|
40-85 °C (depending on pH and degree of methoxylation) |
independant of temp. |
|
|
Melting |
melts below the setting temperature |
yes |
no |
no (but prolonged heating at low/high pH will destabilize gel) |
|
|
Promoter |
alcohol rises setting temperature |
requires calcium ions for gelling; can gel in presence of milk (0.6-0.9% pectin required) |
requires acidity (pH < 3.5) and high sugar contents for gelling (60-80% soluble solids, mainly sugar) |
requires calcium for gelling |
|
|
Inhibitor |
salt lowers setting temperature |
high sugar concentrations, low pH |
|
pH < 4 (is corrected by addition of sodium citrate); gels at too high ion/salt concentrations |
|
|
Tolerates |
acids, bases |
|
|
up to ~50% ethanol (d. and hydrate in water before addition of alcohol) |
acids/bases, salts, heating, enzymes, up to 60% ethanol |
|
Viscosity of solution |
low when cold, high when hot |
low |
low |
low in neutral water, high at lower pH |
high (independent of temperature) |
|
Typical concentration |
1-2% for gels; [0.26-3.4%] |
[0.15-3.1%] |
[0.15-3.1%] |
0.5-1% for normal spherification; [0.3-5%] |
0.25% thin running sauce, 0.7-1.5% thick sauces, 0.5-0.8% foams; [0.08- 0.85%] |
|
Synergies |
guar, locust bean gum, konjac |
||||
|
Syneresis |
yes |
yes |
yes |
yes |
|