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How do ions influence the melting and setting temperatures of gellan gum gels, and what practical application does this enable?

How do ions influence the melting and setting temperatures of gellan gum gels, and what practical application does this enable?

The melting and setting points of gellan gum gels exhibit a strong, predictable dependence on both the type and concentration of cations present. Experimental data indicates that gels formed with calcium ions (Ca²⁺) typically set within a range of 25–40°C, while those formed with sodium ions (Na⁺) set at higher temperatures, between 40–50°C. The ionic concentration has a particularly marked influence on the melting temperature. At lower ion levels, the gels remain thermo-reversible and will re-melt upon heating. However, as the ion concentration increases, the melting point rises significantly. At sufficiently high ion levels, the gels become heat-stable and do not melt below 100°C. This property is critically useful in applications requiring thermal processing, such as in canned foods or bakery products that must withstand high temperatures without losing their gelled structure.


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