
Comparison of hydrocolloid properties -2
|
Name |
gellan (E418) low acyl (LA) |
gellan (E418) high acyl (HA) |
guar gum (E412) |
konjac glucomannan (E425) |
locust (carob) bean gum (E410) |
|
Origin |
polysaccharide obtained by fermentation of Sphingomonas elodea |
polysaccharide obtained by fermentation of Sphingomonas elodea |
polysaccharide extracted from the seeds of the legume Cyamopsis tetragonolobus |
polysaccharide extracted from the tuber Lasioideae Amorphophallus |
polysaccharide extracted from the seeds of the legume Ceratonia siliqua |
|
Properties, texture |
thermoirreversible, hard, brittle gel; sodium/potassium ions give thermoreversible gels |
thermoreversible, soft, elastic gel; thickener if not heated |
very stable, quick acting thickener, suitable for suspending particles |
shear-thinning viscous sol. with fatty mouth feel; thermoreversible elastic gels w. xanthan/kappa carrageenan; thermoirreversible gels at pH 9-10 |
thickener, often used in ice cream; elastic gel in 1:1 ratio with xanthan |
|
Clarity |
transparent |
opaque |
transparent |
transparent |
|
|
Dispersion |
cold water; d. is improved (allowing add. to hot solutions) by mixing with sugar (3-5x), glycerol, alcohol or oils (3-5x); hard water promotes d. |
cold water; d. is improved (allowing add. to hot solutions) by mixing with sugar (3-5x), glycerol, alcohol or oils (3-5x); hard water promotes d. |
cold water, d. is improved by mixing with sugar (3-5x) or small amounts of alcohol |
cold water; d. can be improved by mixing with sugar or flour (3-5x). |
cold water; d. can be improved by mixing with sugar (3-5x). |
|
Hydration (dissolution) |
90-95 °C; keep pH > 3.9; add sugar after hydration; inhibited in presence of sodium and calcium, but 0.1-0.3% sodium citrate helps |
85-95 °C; can be hydrated at pH < 4; less sensitive to ions; add sugar after hydration |
cold or hot water |
cold water with continuous stirring for at least 2h |
> 90 °C |
|
pH |
4-10 |
3-10 |
4-10 |
~3-10 |
|
|
Setting |
10-60 °C, rapid (minutes) |
70-80 °C |
|
|
|
|
Melting |
does not melt |
70-80 °C |
|
w. xanthan: yes, alkaline gels: no |
|
|
Promoter |
gelling promoted by calcium, magnesium, sodium, potassium and acids |
gelling is not sensitive to ions |
|
xanthan, kappa carrageenan |
will only gel in presence of agar, kappa carrageenan or xanthan |
|
Inhibitor |
will not hydrate at pH < 3.9 or with sodium/calcium salts present |
|
low pH |
viscosity decreases with decreasing pH; gelling occurs at higher pH. |
|
|
Tolerates |
|
salts, acidic foods |
salt and sugar |
salt, acidic foods |
|
|
Viscosity of solution |
low |
high |
high in cold low in hot |
low temperature: high high temperature: lower |
low temperature: high highest viscosity obtained > 60 °C |
|
Typical concentration |
0.4-0.7% for gels (self supporting from 0.05%); [0.03-2.6%] |
0.4-0.7% for gels (self supporting from 0.2%); [0.03-2.6%] |
0.2-0.5% (very sticky solutions above 1%) |
0.1-0.3% for viscous solutions |
0.1-1.0% |
|
Synergies |
|
|
locust bean gum, xanthan |
xanthan, kappa carrageenan, locust bean gum |
xanthan, kappa carrageenan |
|
Syneresis |
no (if left untouched) |
no |
|
|
|